Question
How is the Absolute zero obtained from Charles’ law?
Answer
From Charle’s law, we know that, at constant pressure, the volume of a given mass of gas increases or decreases by t/273 part of its volume at 0oC for every 1 degree rise or fall in temperature.
Suppose, the temperature of the same gas is decreased to -toC. So, its volume at that temperature,
Vt = Vo(1+t/273)
From the above equation, it is evident that if the temperature is reduced to -273oC, Vt will be zero.
Based on this observation, a new scale of temperature was adopted with its zero at -273oC. This scale is known as the absolute scale and the zero reading of this scale is known as absolute zero.