An aqueous solution of sugar cannot conduct electricity, but an aqueous solution of sodium chloride can. Why? OR Why is it appropriate to use the term formula weight instead of molecular weight in the case of sodium chloride?
An aqueous solution of sugar cannot conduct electricity because sugar does not dissociate into ions in water. While, sodium chloride (NaCl) dissociates into Na⁺ and Cl⁻ ions, which carry electric current.
OR
It is appropriate to use the term formula weight instead of molecular weight for sodium chloride (NaCl) because NaCl is an ionic compound, not a molecule. Formula weight refers to the sum of the atomic weights of the ions in the formula unit.
Question ID: 80
Uploaded on: September 12, 2024
Compare the following two properties of naphthalene and sodium chloride: melting point and solubility in water.
Naphthalene | Sodium chloride |
Low melting point (about 80°C) | High melting point (about 801°C ) |
Poorly soluble in water due. | Highly soluble in water |
Question ID: 81
Uploaded on: September 12, 2024
Name a gas which can be prepared in Kipp's apparatus.Write the balanced chemical equation of the reaction for the preparation of the gas.
Hydrogen sulfide (H₂S) gas can be prepared in Kipp\'s apparatus.
Balanced Chemical Equation:
FeS + H2SO4 → FeSO4 + H2S ↑
In this reaction, iron(II) sulfide (FeS) reacts with sulfuric acid (H₂SO₄) to produce iron(II) sulfate (FeSO₄) and hydrogen sulfide gas (H₂S).
Question ID: 82
Uploaded on: September 12, 2024
How is metallic zinc obtained from zinc oxide? Write the reaction with a balanced chemical equation. [1 + 1] OR What happens when a piece of zinc is added to an aqueous solution of CuSO₄? Show with the help of electronic theory that this is an oxidation-reduction reaction. [1 + 1]
To obtain metallic zinc from zinc oxide, zinc oxide is reduced by carbon or carbon monoxide. The balanced chemical equation for the reduction of zinc oxide with carbon is:
ZnO + C → Zn + CO
OR
When a piece of zinc is added to an aqueous solution of CuSO₄, zinc displaces copper from the solution, resulting in the formation of zinc sulfate and metallic copper. The balanced chemical equation is:
Zn + CuSO4 → ZnSO4 + Cu
Electronic Theory Explanation:
Oxidation:
Zinc (Zn) loses electrons and is oxidized to Zn²⁺:
Zn → Zn 2+ + 2𝑒−
Reduction:
Copper ions (Cu²⁺) gain electrons and are reduced to metallic copper (Cu):
Cu²⁺ + 2e− → Cu
Question ID: 83
Uploaded on: September 12, 2024
Show with the help of structural formula of ethylene that it is an unsaturated hydrocarbon. OR What is denatured spirit?
Ethylene (C₂H₄) Structural Formula:
H2C=CH2
In ethylene, the two carbon atoms are connected by a double bond. The presence of the double bond indicates that ethylene is an unsaturated hydrocarbon.
OR
To prevent the usage of Ethanol as beverages, a small amount (approximately) of Methanol (CH3OH) is added to it. This makes Ethanol unfit for drinking and is called denatured spirit.
Question ID: 84
Uploaded on: September 12, 2024
State Charles's law is related to gases and represents them graphically (V vs T). [2+1]
Charle's law: At constant pressure, the volume of a given mass of a gas increases or decreases by 1/273 of its volume at 0°C for each one-degree rise or fall in temperature.
The mathematical form of Charle's law:
Vt=Vo(1+t/273)
Vo = volume at 0°C
Vt = volume at t°C
Question ID: 85
Uploaded on: September 13, 2024
How many grams of ammonium sulphate will be required to prepare 6.8 g of ammonia by heating ammonium sulphate with a caustic soda solution? [3] (H = 1, N = 14, O = 16, S = 32) OR CaCl2, CO2 and H2O are produced by the reaction of dilute HCl with CaCO3. How many gram of HCl will be required to prepare 55.5 g of CaCl2, 22.0 g of CO₂ and 9.0 g of H₂O from 50.0 g of CaCO3? What is the number of moles of HCl required? [2+1]
Balanced chemical equation:
(NH4)2SO4 + 2NaOH → 2NH3 +Na2SO4 + 2H2O
Molecular mass of NH3 = 17 g
Molecular mass of (NH4)2SO₄
= [2 × (14 + 4)] + [32 + (4 × 16)]
= 132 g
From the balanced equation, 2 moles of NH₃ are produced from 1 mole of (NH₄)2 SO₄. Therefore, the moles of ammonium sulfate required to produce 0.4 moles of NH₃ are:
Moles of (NH₄)2 SO₄ = 0.4/2 = 0.2 mol
Mass of (NH₄)2SO₄ = 0.2 × 132 = 26.4 g
26.4 g of ammonium sulfate will be required to prepare 6.8 g of ammonia.
Question ID: 86
Uploaded on: September 13, 2024
What is the volume expansion coefficient of a gas at fixed pressure? What is its value? [2+1] OR Mention two similarities between heat conduction and electrical conduction.
The volume expansion coefficient of a gas at constant pressure is the fractional change in volume per unit change in temperature.
At 0°C (273 K), its value is approximately 0.00366 K⁻¹, meaning the gas volume increases by about 0.366% per 1°C increase in temperature at constant pressure.
OR
The two similarities between heat conduction and electrical conduction are
Diamond is a non-metal with very high thermal conductivity.
Question ID: 87
Uploaded on: September 13, 2024
State the two laws of refraction of light. Write also the mathematical form of the second law. [2+1]
The two laws of refraction of light:
Mathematical form of the second law
sin i/ sin r =constant
Question ID: 88
Uploaded on: September 13, 2024
In the case of a concave mirror find the relationship between focal length and radius of curvature. OR A ray of light passes through a prism. Show that the angle of deviation δ = i₁+i₂- A (Symbols have usual meaning).
In an optical system, a ray close to and nearly parallel to the principal axis is known as a paraxial ray.
When a paraxial ray of light OA incidents on a concave of a very small aperture, then it gets reflected along AQ. If the principal focus and centre of curvature of the mirror be F and C respectively then AC being the radius of curvature will act as a normal to the reflecting surface at A.
Hence, at point A, the angle of incidence (i) is equal to the angle of reflection (r) and the reflected ray will meet the principal axis at the principal focus E ∴ OA || XY, AC is the transversal, ∠OAC = ∠FCA = i. Again, ∠FAC is also equal to i, hence ∠FCA =∠FAC ∴ FA = FC.
As the aperture of the mirror is very small and we are considering only the paraxial rays (very close to the principal axis) FA is nearly equal to FP Hence, FP = FC and hence CP = 2FP
∴ r = 2f
∴ radius of curvature of the mirror =2 × focal length of the mirror
OR
Let a ray of monochromatic light OP incidents at P on the refracting face AB at an angle of incidence i1 and suffer refraction from air to glass, bend towards the normal making an angle of refraction equal to r1 and finally travel along the path PQ inside the prism. Again the refracted ray PQ strikes the refracting surface AC of the prism at an angle of incidence r2 and after suffering refraction from glass to air, it emerges out of the prism at an angle of emergence i2.
Here, the angle between the direction of the incident ray and the emergent ray (∠LMQ) is called the angle of deviation (δ) of the ray of light after refraction through the prism and its value is
δ = ∠MPQ + ∠MQP = (i₁- r1)+(i2 - r2)
δ = (i₁+ i2) - (r1 + r2) …(i)
Again, in the quadrilateral APNQ,
∠PAQ + ∠PNQ + 90° + 90° = 360°
or, A + ∠PNQ = 180° [where A = ∠PAQ]
∴ ∠PNQ=180° - A …(ii)
(ii) But in ΔPNQ,
r₁ + r₂ + ∠PNQ = 180°
or, ∠PNQ = 180° - (r₁ + r₂) …(ii)
From equation (ii) and (iii) we get,
A = r₁ + r₂ …(iv)
∴ From equation (i)and (iv) we get,
δ = i₁+ i2 - A (Hence Proved)
Question ID: 89
Uploaded on: September 13, 2024
Write Faraday's laws of electromagnetic induction. What is meant by alternating current? [2+1]
Faraday's law of electromagnetic induction:
Alternating Current: An alternating current can be defined as a current that changes its magnitude and polarity at regular intervals of time.
Question ID: 90
Uploaded on: September 13, 2024
An electric bulb of resistance 440 ohm is connected to 220-volt mains for 10 hours. Find the amount of electrical energy consumed in the BOT unit. [3] OR A metal wire of resistance 6 ohm is stretched so that its length becomes double its original length. What would be the final resistance? [3]
Resistance (R) = 440 ohm
Voltage (V) = 220 V
Time (t) = 10 h
Calculation of power:
P = V^2\over R = 220^2/440 = 110 watts
Calculation of Electrical Energy:
E = P × t
= 110 watts × 10 h
= 1100 Wh
= 1.1 BOT
OR
Initial length = l
Initial area = a
Initial Resistance (R) = ρ l\over a = 6 ohm
New length = 2 × l
New Area = a \over 2
Final Resistance (R') = ρ 2 × l\over {a\over2} = 4 × ρ l\over a = 4 × 6 ohm = 24 ohm
The final resistance of the stretched wire is 24 ohms.
Question ID: 91
Uploaded on: September 14, 2024