Chapter 8.4 – Inorganic Chemistry

Inorganic Chemistry
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Book Name : Madhyamik Physical Science And Environment
Subject : Physical Science
Class : 10 (Madhyamik)
Publisher : Oriental Book Company Pvt. Ltd
Chapter Name : Physical and Chemical Properties of Matter

In-text Questions

Question 8.4.1.1

What happens when ammonium sulphate is heated with caustic soda?

Answer

When ammonium sulfate (NH4)2SO4 is heated with caustic soda (sodium hydroxide, NaOH), a chemical reaction occurs, leading to the formation of ammonia gas (NH3), water (H2O), and sodium sulfate (Na2SO4). The reaction can be represented as follows:

(NH4)2SO4 + 2NaOH → 2 NH3 + 2 H2O + Na2SO4

Question 8.4.1.2  

Why CaO is used for drying NH3 but not conc. H2SO4

Answer

CaO reacts with NH3 to form calcium hydroxide [Ca(OH)2] and ammonium nitrate [NH4NO3]. This reaction removes the moisture content from NH3 and makes it dry. In contrast, when conc. H2SO4 is added to NH3, it reacts with it to form ammonium sulfate [(NH4)2SO4], which is a salt and does not remove moisture content.

Question 8.4.1.3

How will you get nitric oxide from ammonia? 

Answer

Ammonia is oxidized by air in the presence of a catalyst such as platinum or rhodium at a temperature of about 850-1000°C to produce nitrogen and water:

4NH3 + 5O2 → 4NO + 6H2O

Question 8.4.1.4

What are the colours of Fe(OH)3 and Al(OH)3

Answer

The colour of Fe(OH)3 is reddish-brown, while the colour of Al(OH)3 is white.

Question 8.4.1.5

During accidental Leakage of ammonia, the face and eyes should be covered with wet towels, why?

Answer

In case of accidental leakage of ammonia, covering the face and eyes with wet towels can help to reduce the harmful effects of ammonia gas.

Question 8.4.1.6

What is the source of N2 and H2 required for the manufacture of ammonia by Haber’s process? 

Answer

Source of N2: The raw material N2 is obtained by fractional distillation of liquid air.

Source of H2: H2 is obtained from water gas.

Question 8.4.1.7

Mention the catalysts used in Haber’s process. 

Answer

Iron powder

Question 8.4.1.8

Write the conditions of manufacture of urea.

Answer

Conditions of manufacture of urea

  1. The process is carried out at a high temperature of around 170-190°C.
  2. A high pressure of around 100-200 atm is maintained in the reactor.
  3. A catalyst, typically iron oxide, is used to promote the reaction between ammonia and carbon dioxide.
  4. The molar ratio of ammonia to carbon dioxide should be maintained at 3:1.

Question 8.4.2.1

What are the reagents needed to prepare H2S in the laboratory? 

Answer

In the laboratory, H2S can be prepared by reacting a metal sulfide with an acid. The reagents needed are:

  1. Metal sulfide: The most commonly used metal sulfide is ferrous sulfide (FeS), although other metal sulfides such as zinc sulfide (ZnS) or copper sulfide (CuS) can also be used.
  2. Acid: Hydrochloric acid (HCl) or dilute sulfuric acid (H2SO4) can be used to react with the metal sulfide.

Question 8.4.2.2

Name some gases which be prepared in Kipp’s apparatus? 

Answer

Some gases which can be prepared in Kipp’s apparatus are:

  1. Hydrogen sulfide (H2S)
  2. Carbon dioxide (CO2)
  3. Chlorine (Cl2)
  4. Sulfur dioxide (SO2)

Question 8.4.2.3

Mention two physical properties of H2S.

Answer

Two physical properties of H2S are:

  1. H2S is a colourless gas with a characteristic odour of rotten eggs.
  2. It is denser than air and is soluble in water.

Question 8.4.2.4

How will you prove that H2S is acidic? 

Answer

To prove that H2S is acidic, we can perform the following experiment:

  1. Take a small amount of H2S gas in a test tube.
  2. Add a few drops of blue litmus solution to the test tube.
  3. If the H2S gas is acidic, it will react with the blue litmus solution and turn it red.

Question 8.4.2.5

What happens when H2S is passed into an acidified potassium dichromate solution? 

Answer

When H2S is passed into an acidified potassium dichromate (K2Cr2O7) solution, it is oxidized to sulfuric acid (H2SO4) and elemental sulfur (S) is formed.

3H2S (g) + K2Cr2O7 (aq) + 4H2SO4 (aq) → 3S ↓ (s) + Cr2(SO4)3 (aq) + K2SO4 (aq) + 7H2O (l)

Question 8.4.2.6

What happens when H2S is passed into AgNO3 solution? 

Answer

When H2S is passed into AgNO3 solution, a white precipitate of Ag2S (silver sulfide) is formed according to the following chemical equation:

2AgNO3 (aq) + H2S (g) → Ag2S↓ (s) + 2HNO3 (aq)

The white precipitate of Ag2S is insoluble in water and can be used as a confirmatory test for the presence of H2S in a given sample.

Question 8.4.2.7

Mention the toxic effect of H2S.

Answer

H2S (Hydrogen sulfide) is a toxic gas that can cause various harmful effects on human health. Some of the toxic effects of H2S are:

  1. Irritation: H2S gas can cause irritation to the eyes, nose, and throat, leading to inflammation and pain.
  2. Respiratory problems: Inhaling high concentrations of H2S can cause respiratory problems such as shortness of breath, coughing, and wheezing.

Question 8.4.3.1

Nitrogen is not prepared in the laboratory by heating ammonium nitrite directly give reason.

Answer

Nitrogen is not prepared in the laboratory by heating ammonium nitrite directly because it undergoes decomposition in an explosive manner, releasing nitrogen gas along with water vapour and nitrogen oxide gases, which are toxic and can cause harm to human health.

Question 8.4.3.2

Mention two uses of nitrogen. 

Answer

Two uses of nitrogen are:

  1. Nitrogen is used in the manufacturing of ammonia, which is further used in the production of fertilizers.
  2. Nitrogen is used in the food industry as a method of preservation.

Question 8.4.3.3

What happens when nitrogen is heated at high temperatures with oxygen?

Answer

Nitrogen and oxygen react at high temperatures at 3000oC produced by an electric spark to give nitric oxide.

N2 + O2 = 2 NO – Heat

Question 8.4.3.4

 Why nitrogen does not react easily.

Answer

Nitrogen is a very stable molecule due to the strong triple covalent bond between the two nitrogen atoms. This bond requires a large amount of energy to break, making nitrogen a very unreactive element under normal conditions.

Question 8.4.3.5

Why does rainwater during thunderstorms contain traces of HNO3

Answer

Rainwater during thunderstorms contains traces of HNO3 due to the formation of nitrogen oxides (NOx) in the atmosphere by the high-energy electrical discharge of lightning. These NOx species then react with water vapour in the atmosphere to form nitric acid (HNO3), which can dissolve in rainwater and fall to the ground as acidic rain.

Question 8.4.3.6

What is nitrolim? Mention its use.

Answer

The black mixture of calcium cyanamide and carbon is commercially known as nitrolim.

Preparation: When calcium carbide is heated in nitrogen at about 1000°C (1273 K), calcium cyanamide is produced with the separation of carbon.

CaC2 + N2 = CaCN2 + C

Uses: It is largely used as fertilizer.

Question 8.4.4.1

What is the physical state of hydrogen chloride? 

Answer

Hydrogen chloride (HCl) is a gas at room temperature and standard pressure. However, it can be dissolved in water to form hydrochloric acid, which is a liquid.

Question 8.4.4.2

How hydrochloric acid is obtained from NaCl? 

Answer

The NaCl is reacted with sulfuric acid (H2SO4) at a temperature of about 500°C and a pressure of about 2 atm. This produces sodium sulfate (Na2SO4) and hydrogen chloride (HCl) gas.

2NaCl (s) + H2SO4 (l) → Na2SO4 (s) + 2HCl (g)

Question 8.4.4.3

Mention the use of Na2SO4

Answer

The sodium sulphate (Na2SO4) is used as a fining agent in the glass manufacturing process, helping to remove small air bubbles and other impurities from molten glass.

Question 8.4.4.4

How is hydrogen chloride manufactured from its elements? 

Answer

WhatsApp Image 2023 03 06 at 12.45.12 AM

At present HCl is manufactured from H2 and Cl2 is obtained as a byproduct in the manufacture of NaOH by the electrolytic process. An equal volume is heated in an electric chamber.

H2 (g) + Cl2 (g) = 2HCl (g)

The resultant HCl vapour passes out of the acid chamber through an outlet and is cooled by passing through a cooling coil cooled by water. This cooled gas is absorbed in a tower by a shower of water to get a saturated solution of HCl in the water.

Question 8.4.4.5

Give equation and condition the manufacture HCl from Cl2 and H2O. 

Answer

Hydrochloric acid can also be manufactured by passing a mixture of Cl2 and hot water through activated charcoal.

2Cl2 + 2H2O = 4HCl + O2

HCl vapour is absorbed in water and O2 is passed out.

Question 8.4.4.6

The raw materials H2 and Cl2 required to manufacture HCl are obtained as by-products of which industry. 

Answer

The raw materials hydrogen gas (H2) and chlorine gas (Cl2) required to manufacture hydrochloric acid (HCl) are typically obtained as by-products of the chemical industry, especially from the production of chlorine-containing compounds.

Question 8.4.4.7

What is the source of SO2 in the contact process of the manufacture of H2SO4

Answer

At present HCl is manufactured from H2 and Cl2 is obtained as a byproduct in the manufacture of NaOH by the electrolytic process.

Question 8.4.4.8

Name the catalyst used in the conversion of SO2 to SO3

Answer

The catalyst used in the conversion of SO2 to SO3 is vanadium pentoxide (V2O5).

Question 8.4.4.9

What is pyrosulphuric acid? 

Answer

Pyrosulfuric acid, also known as oleum or fuming sulfuric acid, is a highly concentrated form of sulfuric acid (H2SO4) that contains excess sulfur trioxide (SO3). Its chemical formula is H2S2O7.

Question 8.4.4.10

Why SO3 is dissolved in 98% H2SO4 and not in water?

Answer

SO3 is highly reactive and exothermic when it comes in contact with water. When SO3 is added to water, it can produce a highly corrosive mist of sulfuric acid that can cause damage to the equipment and the environment.

Multiple Choice Questions (MCQ)

Question 1

Ammonia can be obtained by heating ammonium sulphate with –

  1. КОН
  2. NaCI
  3. CaCl2
  4. ZnSO4

Answer

CaCl2

Explanation:

Ammonia can be obtained by heating ammonium sulphate with CaCl2.

Question 2

Ammonia is collected by –

  1. downward displacement of water 
  2. downward displacement of air
  3. upward displacement of air
  4. By downward displacement of hot water

Answer

(c) Upward displacement of air

Explanation:

Ammonia is collected by the upward displacement of air.

Question 3

Ammonia is –

  1. basic
  2. acidic
  3. neutral 
  4. Insoluble in water

Answer

(a) basic

Explanation:

Ammonia is a basic compound. When it is dissolved in water, it reacts with water to form ammonium hydroxide, which is a strong base. The chemical equation for this reaction is:

NH3 + H2O → NH4OH

Question 4

Ammonium nitrate and Ca(OH)2 on heating produce –

  1. N2
  2. NO2
  3. NH3
  4. NO

Answer

(c) NH3

Explanation:

Ammonium nitrate and Ca(OH)2 on heating produce NH3 (ammonia). The chemical equation for this reaction is:

Ca(OH)2 + 2NH4NO3 → Ca(NO3)2 + 2H2O + 2NH3

Question 5

Liquid ammonia contains –

  1. 35% NH3
  2. 60% NH3
  3. 80% NH3
  4. 0.0% NH3

Answer

(d) 0.0% NH3

Explanation:

Liquid ammonia contains only NH3 molecules and no other substances. Therefore, the percentage of NH3 in liquid ammonia is 100%, and the other options (35%, 60%, and 80%) are incorrect.

Fill up the blanks

Question

  1. The odour of H2S is like that of ____.
  2. Ammonia is ____ soluble in water.
  3. Ammonia is prepared by heating ammonium salt and ____.
  4. H2S reacts with ____ to give salt.
  5. H2S reacts with AgNO3 solution to give ____ precipitate.
Answer
  1. The odour of H2S is like that of rotten eggs.
  2. Ammonia is highly soluble in water.
  3. Ammonia is prepared by heating ammonium salt and a strong base.
  4. H2S reacts with metal ions to give a salt.
  5. H2S reacts with the AgNO3 solution to give a black precipitate of Ag2S.

Select the correct word from the words in brackets to complete each sentence.

Question
  1. SO2 is converted to SO3 in the presence of ____ catalyst. (Pt / Ni) 
  2. The solid catalysts in a reaction are used in powder form to get ____ surface area. (greater / smaller). 
  3. HNO3 is manufactured from NH3 by ____ process. (Haber / Ostwald). 
  4. The rainwater during thunderstorms is ____ (acidic/basic). 
  5. On heating CaC2 and N2 at 1000°C produce ____ coloured substance. (Black /white)
Answer
  1. SO2 is converted to SO3 in the presence of Pt catalyst.
  2. Solid catalysts in a reaction are used in powder form to get a greater surface area.
  3. HNO3 is manufactured from NH3 by Ostwald process.
  4. The rainwater during thunderstorms is acidic.
  5. On heating CaC2 and N2 at 1000°C, they produce a black colored substance.

Match the Column-1 with Column-2

Column-1 Column-2
(i) Haber’s process (a) Urea
(ii) Ostwald’s process (b) CaNCN
(iii) Dryer of NH3 (c) NH4CI
(iv) Platinum-Rhodium catalyst (d) CaO
(v) CuSO4 solution + NH4OH excess (e) Wet thick cloth
(vi) Brown precipitate (f) deep blue solution
(vii) NH3 leakage (g) Fe(OH)3
(viii) Nitrogen-containing fertilizer (h) Ostwald’s process
(ix) Two gases gives a solid (i) HNO3
(x) Nitrolim (j) NH3

Answer

Column-1 Column-2
(i) Haber’s process (j) NH3
(ii) Ostwald’s process (i) HNO3
(iii) Dryer of NH3 (d) CaO
(iv) Platinum-Rhodium catalyst (h) Ostwald’s process
(v) CuSO4 solution + NH4OH excess (f) Deep blue solution
(vi) Brown precipitate (g) Fe(OH)3
(vii) NH3 leakage (e) Wet thick cloth
(viii) Nitrogen-containing fertilizer (a) Urea
(ix) Two gases gives a solid (c) NH4Cl
(x) Nitrolim (b) CaNCN

Indicate whether the following statements are true or false

Question

  1. Nitrogen is prepared in the laboratory by heating ammonium nitrite. 
  2. Ammonia is highly soluble in water. 
  3. Liquid ammonia contains no water. 
  4. Liquid ammonia and liquor ammonia are the same things. 
  5. Ammonia has no reducing properties.

Answer

  1. False. Nitrogen is prepared in the laboratory by heating ammonium nitrate, not ammonium nitrate.
  2. True. Ammonia is highly soluble in water.
  3. False. Liquid ammonia contains a small amount of water.
  4. False. Liquid ammonia and liquor ammonia are not the same things. Liquor ammonia is a solution of ammonia in water, whereas liquid ammonia is pure ammonia.
  5. False. Ammonia has reducing properties.

Answer the following questions

Question 1

Write a balanced equation for the preparation of ammonia from NH4Cl. 

Answer

Balanced equation:

NH4Cl + NaOH → NH3 + NaCl + H2O

Question 2

Ammonia can be liquified at what temperature and pressure? 

Answer

Ammonia can be liquified at a temperature of -33.34°C and pressure of 8.5 atm.

Question 3

Write an equation to show the reducing property of ammonia. 

Answer

Equation showing reducing property of ammonia: 4NH3 + 3O2 → 2N2 + 6H2O.

Question 4

Write an equation where two gases react to give a solid. 

Answer

Ammonia gas and Hydrogen chloride gas react to form the salt ammonium chloride

NH3 (g) + HCl (g) → NH4Cl (s)

Question 5

How will you identify ammonia with Nessler’s reagent?

Answer

Ammonia can be identified with Nessler’s reagent by the formation of a brown precipitate of a complex between ammonia and mercury ions.

Short Answer Type Questions

Question 1

How hydrogen chloride is prepared from Cl2

Answer

Hydrogen chloride (HCl) can be prepared from chlorine gas (Cl2) through a process known as the “direct combination” or “synthesis” method. Here’s the chemical equation for the reaction:

Cl2(g) + H2(g) → 2HCl(g)

Question 2

Mention conditions to convert SO2 to SO3

Answer

SO2 can be converted to SO3 in the presence of a vanadium(V) oxide catalyst at a temperature of around 450-500°C and a pressure of around 1-2 atm.

Question 3

How NH3 is converted to NO. 

Answer

NH3 is converted to NO by the oxidation process in the presence of a platinum-rhodium catalyst and a temperature range of 800-900°C.

Question 4

Why strong bases like KOH should not be used to prepare ammonia from ammonium salts? 

Answer

Strong bases like KOH should not be used to prepare ammonia from ammonium salts because they can react with NH4+ ions to form NH3 gas, which can escape from the solution and lead to low yields of ammonia.

Question 5

What is liquor ammonia? 

Answer

Liquor ammonia is a concentrated aqueous solution of ammonia containing about 25% to 30% by weight of NH3. It is also known as aqueous ammonia or ammonia water.

Question 6

Give an example of reducing the property of ammonia. 

Answer

An example of the reducing property of ammonia is its reaction with hot copper oxide to form nitrogen gas and water vapour.

CuO + 2NH3 → N2 + 3H2O + Cu

Question 7

What happens when excess ammonia solution is added gradually to an aqueous solution of CuSO4

Answer

When excess ammonia solution is added gradually to an aqueous solution of CuSO4, a deep blue complex known as cuproammonium sulphate is formed.

CuSO4 +  NH4(OH) → [Cu(NH3)4SO4]

Question 8

What happens when ammonium hydroxide is added to an aqueous solution of aluminium chloride?

Answer

When ammonium hydroxide is added to an aqueous solution of aluminium chloride, a white gelatinous precipitate of aluminium hydroxide is formed. The chemical equation for the reaction is:

AlCl3 + 3NH4OH → Al(OH)3 + 3NH4Cl

Question 9

What is Nessler’s reagent? Mention its use. 

Answer

Nessler’s reagent is the alkaline solution of potassium mercuric Iodide (K2[HgI4]).

Its main use is to detect and quantify the presence of ammonia and ammonium ions in a solution, as it forms a brown precipitate of a complex between ammonia and mercury ions.

Question 10

Mention the uses of ammonia.

Answer

Uses of ammonia are:

  1. Ammonia is widely used in the production of fertilizers as a source of nitrogen.
  2. It is used as a refrigerant in industrial refrigeration systems.
  3. Ammonia is used in the production of various chemicals, such as explosives, plastics, and pharmaceuticals.

Long Answer (LA) type Questions

Question 1

Write the principle of the manufacture of ammonia.

Answer

The principle of the manufacture of ammonia is based on the reaction between nitrogen and hydrogen gases in the presence of a catalyst, which produces ammonia. The reaction is exothermic and occurs at high temperatures and pressure. The catalyst used in this reaction is typically a mixture of iron oxide and alumina. The process of manufacturing ammonia is known as the Haber process.

Question 2

What is the difference between liquor and liquid ammonia? 

Answer

Liquor Ammonia Liquid Ammonia
Solution of ammonia gas in water Pure form of ammonia
Contains impurities like other gases and minerals Free from impurities
Used in cleaning agents, fertilizers, and other industrial applications Used as a refrigerant and in the production of pharmaceuticals and plastics

Question 3

What precautions should be taken to combat accidental leakage of ammonia? 

Answer

If there is an accidental leakage of ammonia, the following precautions should be taken:

  1. All personnel should immediately evacuate the area to prevent inhalation of ammonia gas, which can be harmful to health.
  2.  Open all windows and doors to allow fresh air to enter the area and disperse the ammonia gas.
  3. Wear protective gear such as gloves, goggles, and a mask.

Question 4

Describe the principle of large-scale preparation of ammonia. 

Answer

  1. The Haber-Bosch process is the most common method for the large-scale preparation of ammonia.
  2. This process involves reacting nitrogen gas and hydrogen gas at high temperatures (around 450°C) and pressures (around 200-300 atmospheres) in the presence of an iron-based catalyst.
  3. Nitrogen is obtained from the air through a process called fractional distillation, while hydrogen is obtained from natural gas or other sources through a process called steam reforming.
  4. The reactants are compressed and fed into a reactor where they are heated and passed over the catalyst.
  5. The reaction produces ammonia gas, which is cooled and liquefied for storage and transport.

Question 5

How urea is manufactured? 

Answer

In an autoclave ammonia and carbon dioxide are taken in 3:1 molar proportion, the mixture is heated to 170oC – 190oC at a pressure of 100 – 200 atmosphere to give ammonium carbamate (NH4COONH2) on reducing pressure this compound gives up water to produce urea.

2NH3 + CO2 → NH4COONH2 + Heat

NH4COONH2 → NH2CONH2 + H2O + Heat

Question 6

Give the principle to prepare H2S. Mention its reaction with an aqueous solution of CuSO4.

Answer

In the laboratory, H2S is prepared by the action of dilute sulphuric acid with ferrous sulphide at room temperature.

Equation : FeS + H2SO4 → FeSO4 + H2S

When hydrogen sulfide (H2S) reacts with an aqueous solution of CuSO4 (copper sulfate), it forms a precipitate of CuS (copper sulfide) and sulfuric acid (H2SO4) is also produced as a by-product. The balanced chemical equation for this reaction is:

H2S (g) + CuSO4 (aq) → CuS (s)↓ + H2SO4 (aq)

Question 7

Mention the principle of Kipp’s apparatus to prepare gas. 

Answer

kipp gas generator kipps apparatus vintage engraved illustration 1897 2BGPNTJ

The Kipp’s apparatus is a laboratory apparatus used to prepare gases by the reaction of a solid with a liquid. It consists of three interconnected glass bulbs arranged vertically, with the solid in the middle bulb. The upper and lower bulbs are connected by a tube and contain the liquid. The middle bulb has a tube with a tap for drawing off gas.

The principle of the Kipp’s apparatus is as follows:

  • The liquid is poured into the upper bulb.
  • The solid is placed in the middle bulb.
  • The tap is closed.
  • The pressure of the gas in the middle bulb forces the liquid down into the lower bulb.
  • The solid and liquid react to form gas.
  • The gas accumulates in the middle bulb.
  • The tap is opened and the gas is drawn off.

Question 8

Write with equation the following properties of H2S.(i) acidic (ii) reducing and (iii) Precipitation. 

Answer

(i) H2S is acidic and reacts with metal hydroxides to form corresponding sulfides and water. For example, with sodium hydroxide:

H2S (g) + 2 NaOH (aq) → Na2S (aq) + 2H2O (l)

(ii) H2S is a reducing agent and can reduce metal ions to their elemental forms. For example, with silver nitrate:

H2S (g) + 2AgNO3 (aq) → 2Ag (s) + 2HNO3 (aq) + S (s)

(iii) H2S can form insoluble metal sulfides when reacted with metal ions in aqueous solutions. For example, with lead (II) nitrate:

H2S (g) + Pb(NO3)2 (aq) → PbS (s) + 2HNO3 (aq)

Question 9

What is nitrolim? Mention its preparation and uses. 

Answer

The  black mixture of calcium cyanamide and carbon is commercially known as nitrolim.

Preparation: When calcium carbide is heated in nitrogen at about 1000°C (1273 K), calcium cyanamide is produced with the separation of carbon.

CaC2 + N2 = CaCN2 + C

Uses: It is largely used as fertilizer.

Question 10

Write notes about the fixation of aerial nitrogen. 

Answer

Nitrogen fixation is the process of converting atmospheric nitrogen into usable forms for plants and organisms. Certain bacteria can take in atmospheric nitrogen and convert it into ammonia. Aerial nitrogen fixation occurs when bacteria live on the surfaces of leaves, taking in nitrogen and fixing it into a form that can be used by the plant. This process is important in areas with poor soil. Legumes and other plants can host nitrogen-fixing bacteria.

Question 11

Write the principle of the manufacture of H2SO4

Answer

The principle of the manufacture of H2SO4 by the Contact Process involves the following steps:

  1. Preparation of sulfur dioxide (SO2) by burning sulfur or by roasting metal sulfides.
    S + O2 = SO2 (4FeS2 + 11O2 = 2Fe2O3 + 8SO2)
  2. Conversion of SO2 to sulfur trioxide (SO3) by catalytic oxidation with oxygen using a vanadium pentoxide catalyst at a temperature of around 450-500°C.
    2SO2 + O2 = 2SO3 + Heat
  3. Absorption of SO3 in 98% sulfuric acid to produce oleum (a mixture of H2SO4 and SO3).
    H2SO4 + SO3 = H2S2O7
  4. Dilution of oleum with water to obtain the desired concentration of sulfuric acid (typically 98% or 96%).
    H2S2O7 + H2O = 2H2SO4
  5. Recycling of unreacted SO2 and excess oxygen to the oxidation step.

Question 12

How HNO3 is manufactured by Ostwald’s process? 

Answer

HNO3 is manufactured by Ostwald’s Process, which involves the following steps:

  1. Ammonia (NH3) is oxidized to nitrogen monoxide (NO) by heating it in the presence of a platinum-rhodium catalyst at a temperature of around 850-900°C.
    4NH3 (g) + 5O2 (g) → 4NO (g) + 6H2O (g)
  1. The nitrogen monoxide is then oxidized to nitrogen dioxide (NO2) by reacting it with excess oxygen in the presence of a platinum-rhodium catalyst at a temperature of around 450-550°C.
    2NO (g) + O2 (g) → 2NO2 (g)
  1. The nitrogen dioxide is then absorbed in water to form nitric acid (HNO3), which is then concentrated to the desired strength through distillation.
    3NO2 (g) + H2O (l) → 2HNO3 (aq) + NO (g)

Question 13

How HCl is prepared on a large scale from NaCl? 

Answer

An early process to manufacture hydrochloric acid by distilling a mixture of Nacl and concentration H2SO4 at 500oC in a cast iron vessel, provided with delivery tubes. The evolved HCl vapour is absorbed in a series of glazed earthen receivers containing water. This acid contaminated with carried-over H2SO4 is removed by distilling over a mixture of BaCl2 and copper turnings.

2NaCl (s) + H2SO4 (l) → Na2SO4 (s) + 2HCl (g)

Question 14

Why the manufacture of H2SO4 from SO3 in the presence of a catalyst is called a contact process? Why catalysts are taken in powdered form?

Answer

The manufacture of H2SO4 from SO3 in the presence of a catalyst is called a contact process because the reaction between SO2 and O2 takes place on the surface of a catalyst, and the reactants make only brief contact with the catalyst. This process occurs in a series of chambers or containers, and the gases “contact” the catalyst on their way through each chamber.

Catalysts are taken in powdered form to maximize their surface area and increase the number of active sites available for the reaction to occur.


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