[By Lussac’s law]
N2 + 3H2 → 2NH3
1 vol : 3 vol → 2 vol
To calculate the volume of ammonia gas formed.
H2 : NH3
3 : 2
67.2 : x
⇒ x = 2\over 3 × 67.2 = 44.8 lit
Hence, volume of NH3 formed is 44.8 lit.
We know,
H2 : N2
3 : 1
67.2 : x
⇒ x = 1\over 3 × 67.2 = 22.4 lit
∴ nitrogen left = 44.8 – 22.4 = 22.4 lit.
Hence, 22.4 lit of nitrogen remains in the resultant mixture.