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In one of the industrial processes used for manufacture of sodium hydroxide, a gas X is formed as by-product. The gas X reacts with lime water to give a compound Y which is used as a bleaching agent in chemical industry. Identify X and Y giving the chemical equation of the reactions involved.

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Answer

In the manufacture of sodium hydroxide, hydrogen gas and chlorine gas (X) are formed as by-products. When chlorine gas (X) reacts with lime water, it forms calcium oxychloride (bleaching powder) Y. The reactions are

2π‘π‘ŽπΆπ‘™(π‘Žπ‘ž) + 2𝐻2𝑂(𝑙) β†’ 2π‘π‘Žπ‘‚π»(π‘Žπ‘ž) + 𝐢𝑙2(𝑔) + 𝐻2(𝑔)

𝑋 βˆ’ 𝐢𝑙2 (πΆβ„Žπ‘™π‘œπ‘Ÿπ‘–π‘›π‘’ π‘”π‘Žπ‘ 

πΆπ‘Ž(𝑂𝐻)2(𝑠) + 𝐢𝑙2(𝑔) β†’ πΆπ‘Žπ‘‚πΆπ‘™2(𝑠) + 𝐻2𝑂(𝑙)

πΏπ‘–π‘šπ‘’ π‘€π‘Žπ‘‘π‘’π‘Ÿ

π‘Œ βˆ’ πΆπ‘Žπ‘™π‘π‘–π‘’π‘š π‘œπ‘₯π‘¦π‘β„Žπ‘™π‘œπ‘Ÿπ‘–π‘‘π‘’ (π‘π‘™π‘’π‘Žπ‘β„Žπ‘–π‘›π‘” π‘π‘œπ‘€π‘‘π‘’π‘Ÿ)

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A student accidently spilled concentrated H2SO4 on his hand. Before the teacher got to know, his friend washed his hands with water and also with soap but the burning sensation on hand still continued. His friend then rubbed solid sodium bicarbonate on his hand and then washed with water, finally the burning sensation is relieved. Answer the following questions based on the above situation (i) Mention the values shown by student’s friend. (ii) Can you recommend any other substance available in the laboratory which can be used instead of sodium bicarbonate? (iii) Write the chemical reaction involved in the treatment of acid burn with sodium bicarbonate.

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