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Question

State two relevant observations for the reaction:
Ammonium hydroxide solution is added to copper (II) nitrate solution in small quantities and then in excess.

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Answer

Two observations are:

  1. A bluish white ppt. is formed when small amount of ammonium hydroxide is added.
  2. This precipitate turns deep blue when excess of ammonium hydroxide solution is added.

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Action of Ammonium Hydroxide – on solutions of salts

Magnesium chlorideMgCl2 + NH4OH ⟶ ____ + ____ ↓
Iron [II] sulphateFeSO4 + NH4OH ⟶ ____ + ____ ↓
Iron [III] chlorideFeCl3 + NH4OH ⟶ ____ + ____ ↓
Copper [II] sulphateCuSO4 + NH4OH ⟶ ____ + ____ ↓ [Cu(OH)2 + (NH4)2SO4 + NH4OH [in excess] ⟶ ____ + ____]
Zinc sulphateZnSO4 + NH4OH ⟶ ____ + ____ ↓ [Zn(OH)2 +(NH4)2SO4 + NH4OH [in excess] ⟶ ____ + ____]
Lead nitratePb(NO3)2 + NH4OH ⟶ ____ + ____↓

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