Atomic mass of Na = 23u (Given)
Then, gram atomic mass of Na = 23g
Now, 23g of Na contains = 6.022×1023 number of atoms
Thus, 100g of Na contains = {6.022×10^{23} ×100\over23} number of atoms
= 2.6182 × 1024 number of atoms
Again, atomic mass of Fe = 56u (Given)
Then, gram atomic mass of Fe = 56g
Now, 56 g of Fe contains = 6.022×1023 number of atoms
Thus, 100 g of Fe {6.022×10^{23} ×100\over56} number of atoms
= 1.0753 × 1024 number of atoms
Therefore, 100 grams of sodium contain more number of atoms than 100 grams of iron.