Which of the following reactions takes place at the anode during the electroplating of an article with silver?

(a) Ag − 1e⁻ ⟶ Ag¹⁺

(b) Ag + 1e⁻ ⟶ Ag¹⁻

(c) Ag − 1e⁻ ⟶ Ag

(d) None of the above

Assertion (A): In the electrolysis of acidified water, the volume of hydrogen liberated is twice the volume of oxygen formed. Reason (R): Water has hydrogen and oxygen in the ratio of 1:2 by volume. (a) (A) is true but (R) is false. (b) (A) is false but (R) is true. (c) Both (A) and (R) are true and (R) is the correct explanation of (A). (d) Both (A) and (R) are true, but (R) is not the correct explanation of (A).

Assertion (A): Dilute Sulphuric acid is a stronger electrolyte than concentrated Sulphuric acid. Reason (R): Dilute Sulphuric acid has a higher concentration of mobile ions. (a) (A) is true but (R) is false. (b) (A) is false but (R) is true. (c) Both (A) and (R) are true and (R) is the correct explanation of (A). (d) Both (A) and (R) are true, but (R) is not the correct explanation of (A).

With respect to the electrolysis of copper (II) sulphate solution using copper electrodes, which statement is correct? (a) Copper metal is deposited at the negative electrode. (b) Oxygen gas is produced at the positive electrode. (c) The positive electrode increases in mass. (d) The negative electrode decreases in mass.

Answer the following with reference to the electrolytic refining of copper: (a) What is used as the anode? (b) Where is pure copper deposited? (c) Write the cathode reaction.

Match the Column A with Column B: Column A Column B (a) Sodium chloride 1. has two shared pair of electrons (b) Methane 2. has high melting and boiling points (c) Hydrogen chloride gas 3. a greenhouse gas (d) Oxidation reaction 4. has low melting and boiling points (e) Water 5. Zn − 2e− ⟶ Zn2+ 6. S + 2e− ⟶ S2−

Arrange the following according to the instructions given in brackets: (a) C2H2, C3H6, CH4, C2H4 (In the increasing order of the molecular weight) (b) Cu2+, Na+, Zn2+, Ag+ (The order of Preferential discharge at the cathode)

Fill in the blanks by choosing the correct answer from the brackets: (a) During electrolysis, the compound ............... in its molten state liberates reddish brown fumes at the anode. [NaCl/PbBr2] (b) The ion which could be discharged most readily during electrolysis is ............... [Fe2+/Cu2+]

The following sketch illustrates the process of conversion of Alumina to Aluminium: [5] Study the diagram and answer the following: (a) Name the constituent of the electrolyte mixture which has a divalent metal in it. (b) Name the powdered substance ‘X’ sprinkled on the surface of the electrolyte mixture. (c) What is the name of the process? (d) Write the reactions taking place at the electrodes ‘Y’ (anode) and ‘Z’ (cathode) respectively.

Aqueous copper (II) sulphate is electrolysed using copper electrodes. Which statement about the electrolysis is not correct? (a) An oxidation reaction occurs at the positive electrode. (b) The current is carried through the electrolyte by ions. (c) The positive electrode loses mass. (d) The number of copper (II) ions in the electrolyte decreases.

Match Column A with Column B: Column A Column B (a) CuO + C ⟶ Cu + CO 1. Oxidation (b) Al3+ + 3e− ⟶ Al 2. Ionisation (c) PbBr2 ⟶ Pb2+ + 2Br1− 3. Reduction (d) 2O2− − 2e− ⟶ O2 4. Redox (e) HCl ⟶ H+ + Cl1− 5. Electrolytic dissociation

State the terms for the following: (a) The group obtained by removing one hydrogen atom from the parent alkane. (b) Two metal plates or wires through which the current enters and leaves the electrolytic cell. (c) The amount of substance which contains the same number of units as the number of atoms in carbon-12. (d) The tendency of an atom to pull a shared pair of electrons towards itself in a compound. (e) The formula which represents the simplest ratio between the atoms of elements present in a compound.

K, L and M are beakers containing three different solutions as shown below. Name the beaker which: (a) contains only ions. (b) contains only molecules. (c) has pH less than 7.