Metals from K to Al, are most electropositive, have strong affinity for oxygen hence, they cannot be reduced by reducing agents like coke. They can be reduced by electrolysis only.
Question
Give reasons for the following: Oxides or halides of highly electropositive metals e.g. K, Na, Ca, Al are reduced to metals by electrolysis and not by reduction with coke.
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Give reasons for the following pertaining to Hall Herault’s process. (i) The fusion temperature of the electrolyte has to be lowered before conducting the electrolytic reduction. (ii) The constituents of the electrolyte in addition to one part of fused alumina contains three parts of cryolite and one part of fluorspar. (iii) A layer of powdered coke sprinkled over the electrolytic mixture, protects the carbon electrodes. (iv) It is preferred to use a number of graphite electrodes as anode, instead of a single graphite electrode.
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