Calcination is carried out on carbonates and hydrated ores, where water of hydration and other volatile impurities get removed. Calcination of carbonate ores gives out carbon dioxide. Hence, the ore is heated in absence of air. On the other hand, sulphide ores are generally roasted so that sulphur present as impurity in the ore is given out as sulphur dioxide. Hence, roasting is carried out in the presence of excess air.
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