QQuestion
Give one relevant observation for the following:
(a) Sodium hydroxide is added dropwise to Calcium nitrate solution.
(b) Dilute Hydrochloric acid is added to Iron (II) sulphide.
(c) An amphoteric metal is added to hot concentrated alkali.
Exam-ready answer • 03 Mark
✓Answer
(a) A white precipitate of calcium hydroxide is formed, which is insoluble in excess sodium hydroxide.
Ca(NO3)2 + 2NaOH ⟶ Ca(OH)2 ↓ [white ppt.] + 2NaNO3
(b) A colourless gas with the smell of rotten eggs, hydrogen sulphide (H2S), is evolved with effervescence.
FeS + 2HCl ⟶ FeCl2 + H2S ↑
(c) The amphoteric metal (e.g., zinc or aluminium) dissolves in the hot concentrated alkali showing vigorous effervescence (bubbling) due to the evolution of a colourless, odourless gas. This gas burns with a “pop” sound when a burning splinter is brought near the mouth of the test tube, confirming it is hydrogen.
Zn + 2NaOH ⟶ Na2ZnO2 (sodium zincate) + H2 ↑
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