One gram of gold sample will contain 90/100 = 0.9 g of gold
Number of moles of gold = Mass of gold / Atomic mass of gold
= 0.9/197
= 0.0046
One mole of gold contains NA atoms = 6.022 x 1023
∴ 0.0046 mole of gold will contain = 0.0046 × 6.022 × 1023
= 2.77 x 1021 atoms